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  7. 2-Bromopropionyl bromide, 97%, Thermo Scientific Chemicals

2-Bromopropionyl bromide, 97%, Thermo Scientific Chemicals

Product Code. 11400697
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Quantity:
100 g
500 g

Description

2-Bromopropionyl bromide is used in the preparation of cellulose macroinitiator through direct acylation of cellulose in ionic liquid 1-allyl-3-methylimidazolium chloride. It is also used to prepare 3-(2-bromopropionyl)-2-oxazolidone derivatives and bromoester terminated poly(3-hexylthiophene). Further, it is used as a macroinitiator for atom transfer radical polymerization of acrylates.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
2-Bromopropionyl bromide is used in the preparation of cellulose macroinitiator through direct acylation of cellulose in ionic liquid 1-allyl-3-methylimidazolium chloride. It is also used to prepare 3-(2-bromopropionyl)-2-oxazolidone derivatives and bromoester terminated poly(3-hexylthiophene). Further, it is used as a macroinitiator for atom transfer radical polymerization of acrylates.

Solubility
Miscible with trichloromethane, diethyl ether, benzene and acetone.

Notes
Incompatible with water, alcohols, oxidizing agents and strong alkalis.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 563-76-8
Molecular Formula C3H4Br2O
Molecular Weight (g/mol) 215.872
MDL Number MFCD00000142
InChI Key ILLHORFDXDLILE-UHFFFAOYSA-N
Synonym 2-bromopropionyl bromide, propanoyl bromide, 2-bromo, 2-bromopropionylbromide, 2-bromo propionyl bromide, 2-bromopropionic acid bromide, .alpha.-bromopropionyl bromide, 2-bromopropanyl bromide, a-bromopropionyl bromide, 2-bromo-propionyl bromide, alpha-bromopropionylbromide
PubChem CID 79047
IUPAC Name 2-bromopropanoyl bromide
SMILES CC(C(=O)Br)Br

Specifications

Density 2.061
Boiling Point 48°C to 50°C (10 mmHg)
Flash Point >110°C (230°F)
Refractive Index 1.521
Quantity 100 g
UN Number UN3265
Beilstein 1071331
Sensitivity Moisture sensitive
Solubility Information Miscible with trichloromethane,diethyl ether,benzene and acetone.
Formula Weight 215.88
Percent Purity 97%
Chemical Name or Material 2-Bromopropionyl bromide
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Safety and Handling

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Signal Word
  • Danger
 Hazard Category
  • Acute toxicity Category 4
  • Serious eye damage/eye irritation Category 1
  • Skin corrosion/irritation Category 1 B
  • Skin sensitiser Category 1
 Hazard Statement
  • H302-Harmful if swallowed.
  • H314-Causes severe skin burns and eye damage.
  • H317-May cause an allergic skin reaction.
  • H318-Causes serious eye damage.
 Precautionary Statement
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
  • P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P310-Immediately call a POISON CENTER/doctor/.
 Supplemental information
  • MIXTURE LIST-Contains : 2-Bromopropionyl bromide

RUO – Research Use Only

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