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3-Aminocrotononitrile, (E)+(Z), 96%, Thermo Scientific Chemicals Product Code.: 11337395
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3-Aminocrotononitrile, (E)+(Z), 96%, Thermo Scientific Chemicals

Product Code. 11337395
500 g
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100 g
500 g
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Product Code. 11337395

Brand: Thermo Scientific Alfa Aesar L05316.36

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Description

3-Aminocrotononitrile reacts with ferrocenyl-1,2-enones to form ferrocenyl pyridines. It undergoes diazotization coupling reaction with p-substituted anilines to give 2-arylhydrazone-3-ketimino-butyronitriles.3-Aminocrotononitrile, (E)+(Z), is used in reaction with aryldiazonium salts gave, instead of the expected triazene, 2-arylhydrazono-3-ketobutyronitrile by electrophilic attack at the ?-carbon and hydrolysis of the resulting imine. It is also used as an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. 3-Aminocrotononitrile was used as bisnucleophilic reagent which on cyclocondensation with hexafluoroacetone(ethoxycarbonylimine) forms bis(trifluoromethyl)pyrimidinones.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
3-Aminocrotononitrile reacts with ferrocenyl-1,2-enones to form ferrocenyl pyridines. It undergoes diazotization coupling reaction with p-substituted anilines to give 2-arylhydrazone-3-ketimino-butyronitriles.3-Aminocrotononitrile, (E)+(Z), is used in reaction with aryldiazonium salts gave, instead of the expected triazene, 2-arylhydrazono-3-ketobutyronitrile by electrophilic attack at the ɑ-carbon and hydrolysis of the resulting imine. It is also used as an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. 3-Aminocrotononitrile was used as bisnucleophilic reagent which on cyclocondensation with hexafluoroacetone(ethoxycarbonylimine) forms bis(trifluoromethyl)pyrimidinones.

Solubility
Very soluble in water, soluble in ethanol.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 1118-61-2
Molecular Formula C4H6N2
Molecular Weight (g/mol) 82.11
MDL Number MFCD00008071,MFCD00008071
InChI Key DELJOESCKJGFML-DUXPYHPUSA-N
Synonym 3-aminocrotononitrile, 2z-3-aminobut-2-enenitrile, 3-amino-2-butenenitrile, z-3-aminobut-2-enenitrile, beta-aminocrotononitrile, 3-amino-2-butenonitrile, 2-amino-1-propenecarbonitrile, 3-amino-crotononitrile, beta-amino-crotononitrile, 2z-3-amino-2-butenenitrileShow MoreShow Less
PubChem CID 5325263
IUPAC Name (Z)-3-aminobut-2-enenitrile
SMILES C\C(N)=C/C#N

Specifications

Melting Point ∼70°C to 75°C
Boiling Point 120°C (4 mmHg)
Flash Point 154°C (309°F)
Quantity 500 g
Beilstein 1719815
Solubility Information Very soluble in water,soluble in ethanol.
Formula Weight 82.11
Percent Purity 96%
Chemical Name or Material 3-Aminocrotononitrile, (E)+(Z)

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Lot Number Certificate Type Date Catalog Number
Lot NumberA0252699 Certificate TypeCertificate of Analysis Date12/04/2024 Catalog NumberL05316.22,L05316.36
Lot Number10208358 Certificate TypeCertificate of Analysis Date06/12/2021 Catalog NumberL05316.22,L05316.36
Lot Number10114174 Certificate TypeCertificate of Analysis Date06/12/2021 Catalog NumberL05316.22,L05316.36
Lot Number10134604 Certificate TypeCertificate of Analysis Date06/12/2021 Catalog NumberL05316.22,L05316.36
Lot Number10192225 Certificate TypeCertificate of Analysis Date06/12/2021 Catalog NumberL05316.22,L05316.36

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