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Benzyl bromide, 99%, Thermo Scientific Chemicals

Product Code. 11405653
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50 g
250 g
1000 g

Benzyl bromide is widely useful in organic synthesis as a benzyl protecting group for alcohols and carboxylic acids. It is used in the preparation of foaming and frothing agents, quaternary ammonium compounds, peniclins, photographic chemicals, synthetic resins, dyes and plasticizers and esters. It is also involved in the synthesis of (E)-(2-Iodovinyl)benzene by reacting it with diiodomethane.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Benzyl bromide is widely useful in organic synthesis as a benzyl protecting group for alcohols and carboxylic acids. It is used in the preparation of foaming and frothing agents, quaternary ammonium compounds, peniclins, photographic chemicals, synthetic resins, dyes and plasticizers and esters. It is also involved in the synthesis of (E)-(2-Iodovinyl)benzene by reacting it with diiodomethane.

Solubility
Miscible with benzene, carbon tetrachloride, ethanol and ether.

Notes
Light and moisture sensitive. Incompatible with bases, alcohols, amines, oxidizing agents and corrodes steel.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 100-39-0
Molecular Formula C7H7Br
Molecular Weight (g/mol) 171.037
MDL Number MFCD00000172
InChI Key AGEZXYOZHKGVCM-UHFFFAOYSA-N
Synonym benzyl bromide, bromomethyl benzene, alpha-bromotoluene, bromophenylmethane, benzene, bromomethyl, phenylmethyl bromide, 1-bromotoluene, benzylbromide, cyclite
PubChem CID 7498
ChEBI CHEBI:59858
IUPAC Name bromomethylbenzene
SMILES C1=CC=C(C=C1)CBr

Specifications

Melting Point -4°C
Density 1.438 g/mL
Boiling Point 198°C to 199°C
Flash Point 87°C (189°F)
Assay Percent Range 99%
Refractive Index 1.575
Quantity 50 g
Beilstein 385801
Sensitivity Moisture sensitive
Solubility Information Miscible with benzene,carbon tetrachloride,ethanol and ether.
Formula Weight 171.04
Physical Form Liquid
Chemical Name or Material Benzyl Bromide
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compliance-icons
Product Identifier
  • Benzyl bromide
Signal Word
  • Warning
Hazard Category
  • Skin corrosion/irritation Category 2
  • Serious eye damage/eye irritation Category 2
  • Specific target organ toxicity Category 3
Hazard Statement
  • H315-Causes skin irritation.
  • H319-Causes serious eye irritation.
  • H335-May cause respiratory irritation.
Precautionary Statement
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P308-IF exposed or concerned:.
  • P310-Immediately call a POISON CENTER/doctor/.

RUO – Research Use Only

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